Chiral Metal Phosphate Catalysis: Highly Asymmetric Hetero-Diels–Alder Reactions

Document Type

Article

Publication Date

2014

Digital Object Identifier (DOI)

https://doi.org/10.1039/C4CC06520D

Abstract

We report a highly enantioselective hetero-Diels–Alder reaction of α-keto esters and isatins catalyzed by chiral calcium BINOL-derived phosphates. The structure of the catalyst is detailed by X-ray crystal structure analysis.

Was this content written or created while at USF?

Yes

Citation / Publisher Attribution

Chemical Communication, v. 50, p. 14187-14190

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