Gold Redox Catalysis for Cyclization/Arylation of Allylic Oximes: Synthesis of Isoxazoline Derivatives
Document Type
Article
Publication Date
2019
Digital Object Identifier (DOI)
https://doi.org/10.1039/C9CC02830G
Abstract
Base-assisted diazonium activation has been employed to promote gold(I)/(III) redox catalysis toward allylic oxime cyclization/aryl coupling. Functional isoxazolines were prepared with good to excellent yields, while the alternative photoactivation method provided trace amounts of the isoxazoline products. This study further broadens the scope of gold redox chemistry.
Was this content written or created while at USF?
Yes
Citation / Publisher Attribution
Chemical Communication, v. 55, p. 8150-8153
Scholar Commons Citation
Jimoh, Abiola Azeez; Hosseyni, Seyedmorteza; Ye, Xiaohan; Wojtas, Lukasz; Hu, Yong; and Shi, Xiaodong, "Gold Redox Catalysis for Cyclization/Arylation of Allylic Oximes: Synthesis of Isoxazoline Derivatives" (2019). Chemistry Faculty Publications. 148.
https://digitalcommons.usf.edu/chm_facpub/148
