Volatiles in Melt Inclusions from Mexican and Nicaraguan Volcanoes: Implications for Complex Degassing Processes

Authors

Zachary D. Atlas, University of MiamiFollow

Document Type

Dissertation

Publication Date

8-4-2008

Keywords

Magmatic Plumbing Systems, Volcanic Degassing, Melt Inclusions, Central America

Abstract

The first section of this work examines melt inclusions in phenocrysts from Volcán Popocatépetl and Volcán de Colima within the Trans Mexican Volcanic Belt (TMVB). These inclusions are dacitic to rhyolitic. Trends in melt inclusion major element and water concentrations form the evolved extension of other Mexican volcanics including those presumably derived directly from primitive melts. Water concentrations in Popocatépetl and Colima melt inclusions are similar (0.3 to 3.4 weight percent H₂O). Melt-vapor equilibration pressures calculated from dissolved H₂O and COsub2 (Popocatépetl) or H₂O (Colima) in melt inclusions correspond to depths of entrapment of 12 km or less. Water and carbon dioxide concentrations correlate negatively with SiO₂ and potassium. Normalized olivine-augite-quartz compositions are consistent with near cotectic crystallization under vapor-saturated conditions at pressures of 1.5 kb or less. Our results show that Popocatépetl and Colima magmas have undergone vapor-saturated crystallization during ascent in conjunction with varying degrees of mixing between degassed rhyo-dacitic and less degassed, mafic melts in the upper portions of the crust. These data suggest melt evolution occurred in conduits or inter-fingered dikes rather than a large stratified magma chamber. Part II looks at the Masaya caldera in Nicaragua. This volcano has erupted frequently in recorded history, producing lava lakes and very high gas emissions. Melt inclusions from Masaya are basaltic, with low H₂O (below 0.5 wt. %), low S (less than 300 ppm) and high CO₂ concentrations (up to approximately 6000 ppm). Relationships between water, sulfur, Cl and F in combination with Masaya's high CO₂ and Ba/Zr and Ba/Nb ratios suggest that Masaya has undergone a multi stage degassing process involving 1) shallow degassing, 2) recycling of magma into a deeper reservoir, and 3) fluxing of previously degassed magma with a nearly pure CO₂ vapor. Trace element signatures of melt inclusions are consistent with contributions that have been variably metasomatized by fluids generated by dehydration of subducted sediments and/or altered oceanic crust.

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Citation / Publisher Attribution

Volatiles in Melt Inclusions from Mexican and Nicaraguan Volcanoes: Implications for Complex Degassing Processes, 131 p.

Scholar Commons Citation

Atlas, Zachary D., "Volatiles in Melt Inclusions from Mexican and Nicaraguan Volcanoes: Implications for Complex Degassing Processes" (2008). School of Geosciences Faculty and Staff Publications. 1627.
https://digitalcommons.usf.edu/geo_facpub/1627