Graduation Year

2025

Document Type

Thesis

Degree

M.S.C.S.

Degree Name

MS in Computer Science (M.S.C.S.)

Degree Granting Department

Computer Science and Engineering

Major Professor

Lawrence Hall, Ph.D.

Committee Member

Dimitry B. Goldgof, Ph.D.

Committee Member

Shaun Canavan, Ph.D.

Keywords

AI Aided Molecular Design, Data Efficient Design, Deep Neural Network, Priming and Tuning

Abstract

In polymer chemistry, compatibilization involves adding a substance often a block or graft copolymerto stabilize polymer blends that would otherwise not mix well, leading to rough structures and weak me- chanical properties. Compatibilizers improve miscibility and reduce interfacial tension, which is critical for applications such as mixed-waste polymer recycling. Sequence-controlled polymers offer unique potential by combining the tunable chemistry of synthetic polymers with the precise, function-driven design of biological macromolecules, but unlike proteins, they lack large, evolution-shaped datasets to guide discovery. This research develops a deep learning framework to predict the surface tension of sequence-controlled copolymer compatibilizers across varying concentrations. Measuring surface tension experimentally is time-consuming, so we evaluate several machine learning approaches and find deep neural networks most effective, achieving an R2 of 0.91. To address data scarcity, we propose a priming-and-tuning strategy, where a model trained on a low-fidelity sequence–property dataset is efficiently fine-tuned for high-fidelity predictions under new con- ditions. This reduces data requirements, accelerates the design of polymer compatibilizers, and demonstrates the broader potential of AI-guided molecular desig

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