Electron Injection Study of Photoexcitation Effects on Supported Subnanometer Pt Clusters for CO₂ Photoreduction

Authors

Chi-Ta Yang, University of South FloridaFollow
Brandon C. Wood, Lawrence Livermore National Laboratory
Venkat R. Bhethanabotla, University of South FloridaFollow
Babu Joseph, University of South FloridaFollow

Document Type

Article

Publication Date

2018

Digital Object Identifier (DOI)

https://doi.org/10.1039/C8CP00619A

Abstract

Using density functional theory, we study the effect of injected electrons (simulating photoexcited electrons) on the energetics, structures, and binding sites available to CO₂ molecules on subnanometer Pt clusters decorated onto anatase TiO₂(101) surfaces, shedding light on the first and key step of CO₂ photoreduction. Upon the addition of one, two, or three electrons, the O–C–O angles of adsorbed CO₂ become progressively smaller in binding sites that directly contact Pt clusters, while no significant change is found in the intra bond length of the adsorbed CO₂ and in the bonding distances between the adsorbed CO₂ and supported clusters. The extra electrons lead to the stabilization of adsorption sites identified on neutral slabs, including previously metastable configurations, suggesting the enhancement of accessible CO₂ binding sites. Furthermore, supported clusters are able to populate the electronic states of adsorbed CO₂ species, facilitating the formation of the CO₂− anion. To help interpret experimentally observed frequencies, conversion factors are proposed to gain insight into the charge state and O–C–O angle of the adsorbed CO₂. Interestingly, upon electron addition, cluster reconstruction may exist due to the bonding inclination between CO₂ and atoms in the Pt cluster, further stabilizing the intermediate complexes. Finally, the rate-limiting step (C–O bond cleavage) in the CO₂ dissociation to CO is slightly reduced by the introduction of an extra electron. Our results show that subnanometer metal cluster based photocatalysts are good candidates for CO₂ photoreduction.

Was this content written or created while at USF?

Yes

Citation / Publisher Attribution

Physical Chemistry Chemical Physics, v. 20, p. 15926-15938

Scholar Commons Citation

Yang, Chi-Ta; Wood, Brandon C.; Bhethanabotla, Venkat R.; and Joseph, Babu, "Electron Injection Study of Photoexcitation Effects on Supported Subnanometer Pt Clusters for CO₂ Photoreduction" (2018). Chemical, Biological and Materials Engineering Faculty Publications. 20.
https://digitalcommons.usf.edu/ech_facpub/20