Evaluation of the CuCl+ Stability Constant and Molar Absorptivity in Aqueous Media
Copper, molar absorptivity, complexation, spectroscopy, copper and magnesium chloride
Digital Object Identifier (DOI)
Upper and lower bound estimates of the CuCl+ stability constants produced by various investigations have been quantitatively examined. Our analyses, including our own ultraviolet spectroscopic investigations, indicate that the CuCl+ stability constant in 1 molar HClO4 is β1=0.70±0.23. The CuCl+ molar absorptivity at a wavelength of 250 nm was determined as 1860 cm2-mol−1. Our analyses suggest the bound β ′≤0.371 for the formation constant of MgCl+ at one molar ionic strength.
Was this content written or created while at USF?
Citation / Publisher Attribution
Journal of Solution Chemistry, v. 12, p. 581-596
Scholar Commons Citation
Byrne, Robert H.; van der Weijden, Cornelis H.; Kester, Dana R.; and Zuehlke, Richard W., "Evaluation of the CuCl+ Stability Constant and Molar Absorptivity in Aqueous Media" (1983). Marine Science Faculty Publications. 1668.