Spontaneous Formation of a Cross-Linked Supramolecular Polymer Both in the Solid State and in Solution, Driven by Platinum(II) Metallacycle-Based Host–Guest Interactions
Document Type
Article
Publication Date
2019
Digital Object Identifier (DOI)
https://doi.org/10.1021/jacs.9b02281
Abstract
The recent progress in platinum(II) coordination-driven supramolecular polymers has had a substantial effect on the design of functional soft materials. However, the prospect of realizing polymerization induced by platinum(II) metallacycle-based host–guest interactions has received little attention until recently. Here we report the realization of supramolecular polymerization driven by platinum(II) metallacycle-based host–guest interactions both in the solid state and in solution. On the basis of the disclosed polymerization mechanism, we present a new strategy for the preparation of platinum(II) metallacycle-based supramolecular polymers.
Was this content written or created while at USF?
Yes
Citation / Publisher Attribution
Journal of the American Chemical Society, v. 141, issue 16, p. 6494-6498
Scholar Commons Citation
Shi, Bingbing; Liu, Yuezhou; Zhu, Huangtianzhi; Vanderlinden, Ryan T.; Shangguan, Liqing; Ni, Ruidong; Acharyya, Koushik; Tang, Jian-Hong; Zhou, Zhixuan; Li, Xiaopeng; Huang, Feihe; and Stang, Peter J., "Spontaneous Formation of a Cross-Linked Supramolecular Polymer Both in the Solid State and in Solution, Driven by Platinum(II) Metallacycle-Based Host–Guest Interactions" (2019). Chemistry Faculty Publications. 201.
https://digitalcommons.usf.edu/chm_facpub/201
