Title

Spontaneous Formation of a Cross-Linked Supramolecular Polymer Both in the Solid State and in Solution, Driven by Platinum(II) Metallacycle-Based Host–Guest Interactions

Document Type

Article

Publication Date

2019

Digital Object Identifier (DOI)

https://doi.org/10.1021/jacs.9b02281

Abstract

The recent progress in platinum(II) coordination-driven supramolecular polymers has had a substantial effect on the design of functional soft materials. However, the prospect of realizing polymerization induced by platinum(II) metallacycle-based host–guest interactions has received little attention until recently. Here we report the realization of supramolecular polymerization driven by platinum(II) metallacycle-based host–guest interactions both in the solid state and in solution. On the basis of the disclosed polymerization mechanism, we present a new strategy for the preparation of platinum(II) metallacycle-based supramolecular polymers.

Was this content written or created while at USF?

Yes

Citation / Publisher Attribution

Journal of the American Chemical Society, v. 141, issue 16, p. 6494-6498

Share

COinS