Title

Gold Redox Catalysis for Cyclization/Arylation of Allylic Oximes: Synthesis of Isoxazoline Derivatives

Document Type

Article

Publication Date

2019

Digital Object Identifier (DOI)

https://doi.org/10.1039/C9CC02830G

Abstract

Base-assisted diazonium activation has been employed to promote gold(I)/(III) redox catalysis toward allylic oxime cyclization/aryl coupling. Functional isoxazolines were prepared with good to excellent yields, while the alternative photoactivation method provided trace amounts of the isoxazoline products. This study further broadens the scope of gold redox chemistry.

Was this content written or created while at USF?

Yes

Citation / Publisher Attribution

Chemical Communication, v. 55, p. 8150-8153

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